Reactivity of a Dinuclear Pd(I) Complex [Pd(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] with PPh(3): Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc)(2)/nPPh(3) Catalyst System

[Image: see text] [Pd(I)(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] is the reduction product of Pd(II)(OAc)(2)(PPh(3))(2), generated by reaction of ‘Pd(OAc)(2)’ with two equivalents of PPh(3). Here, we report that the reaction of [Pd(I)(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] with PPh(3) results in a nuanced dis...

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Detalles Bibliográficos
Autores principales: Scott, Neil W. J., Ford, Mark J., Husbands, David R., Whitwood, Adrian C., Fairlamb, Ian J. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8441971/
https://www.ncbi.nlm.nih.gov/pubmed/34539028
http://dx.doi.org/10.1021/acs.organomet.1c00347

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8441971/
https://www.ncbi.nlm.nih.gov/pubmed/34539028
http://dx.doi.org/10.1021/acs.organomet.1c00347

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