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Reactivity of a Dinuclear Pd(I) Complex [Pd(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] with PPh(3): Implications for Cross-Coupling Catalysis Using the Ubiquitous Pd(OAc)(2)/nPPh(3) Catalyst System
[Image: see text] [Pd(I)(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] is the reduction product of Pd(II)(OAc)(2)(PPh(3))(2), generated by reaction of ‘Pd(OAc)(2)’ with two equivalents of PPh(3). Here, we report that the reaction of [Pd(I)(2)(μ-PPh(2))(μ(2)-OAc)(PPh(3))(2)] with PPh(3) results in a nuanced dis...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8441971/ https://www.ncbi.nlm.nih.gov/pubmed/34539028 http://dx.doi.org/10.1021/acs.organomet.1c00347 |