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On the limit of proton-coupled electronic doping in a Ti(iv)-containing MOF

Ti(IV)-containing metal–organic frameworks are known to accumulate electrons in their conduction bands, accompanied by protons, when irradiated in the presence of alcohols. The archetypal system, MIL-125, was recently shown to reach a limit of 2e(−) per Ti(8) octomeric node. However, the origin of t...

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Detalles Bibliográficos
Autores principales: Mancuso, Jenna L., Fabrizio, Kevin, Brozek, Carl K., Hendon, Christopher H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442679/
https://www.ncbi.nlm.nih.gov/pubmed/34659715
http://dx.doi.org/10.1039/d1sc03019a