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On the limit of proton-coupled electronic doping in a Ti(iv)-containing MOF
Ti(IV)-containing metal–organic frameworks are known to accumulate electrons in their conduction bands, accompanied by protons, when irradiated in the presence of alcohols. The archetypal system, MIL-125, was recently shown to reach a limit of 2e(−) per Ti(8) octomeric node. However, the origin of t...
Autores principales: | Mancuso, Jenna L., Fabrizio, Kevin, Brozek, Carl K., Hendon, Christopher H. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442679/ https://www.ncbi.nlm.nih.gov/pubmed/34659715 http://dx.doi.org/10.1039/d1sc03019a |
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