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One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds
One-electron chemical reduction of 10-(dimesitylboryl)-N,N-di-p-tolylbenzo[c]phenanthrene-4-amine (3-B(Mes)(2)-[4]helix-9-N(p-Tol)(2)) 1 and 13-(dimesitylboryl)-N,N-di-p-tolyldibenzo[c,g]phenanthrene-8-amine (3-B(Mes)(2)-[5]helix-12-N(p-Tol)(2)) 2 gives rise to monoanions with extensive delocalizati...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442707/ https://www.ncbi.nlm.nih.gov/pubmed/34659727 http://dx.doi.org/10.1039/d1sc02409d |