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One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds

One-electron chemical reduction of 10-(dimesitylboryl)-N,N-di-p-tolylbenzo[c]phenanthrene-4-amine (3-B(Mes)(2)-[4]helix-9-N(p-Tol)(2)) 1 and 13-(dimesitylboryl)-N,N-di-p-tolyldibenzo[c,g]phenanthrene-8-amine (3-B(Mes)(2)-[5]helix-12-N(p-Tol)(2)) 2 gives rise to monoanions with extensive delocalizati...

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Detalles Bibliográficos
Autores principales: Jia, Xiangqing, Nitsch, Jörn, Wu, Zhu, Friedrich, Alexandra, Krebs, Johannes, Krummenacher, Ivo, Fantuzzi, Felipe, Braunschweig, Holger, Moos, Michael, Lambert, Christoph, Engels, Bernd, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442707/
https://www.ncbi.nlm.nih.gov/pubmed/34659727
http://dx.doi.org/10.1039/d1sc02409d