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Rigid, biconical hydrogen-bonded dimers that strongly encapsulate cationic guests in solution and the solid state

The octol of a new rigid, tetraarylene-bridged cavitand was investigated for self-assembly behaviour in solution. (1)H and DOSY NMR spectroscopic experiments show that the cavitand readily dimerizes through an unusual seam of interdigitated hydrogen-bonds that is resistant to disruption by polar co-...

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Detalles Bibliográficos
Autores principales: Smith, Jordan N., Ennis, Courtney, Lucas, Nigel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442710/
https://www.ncbi.nlm.nih.gov/pubmed/34659726
http://dx.doi.org/10.1039/d1sc01802g