Me(3)SiSiMe(2)(O(n)Bu): a disilane reagent for the synthesis of diverse silacycles via Brook- and retro-Brook-type rearrangement

Herein, a readily available disilane Me(3)SiSiMe(2)(O(n)Bu) has been developed for the synthesis of diverse silacycles via Brook- and retro-Brook-type rearrangement. This protocol enables the incorporation of a silylene into different starting materials, including acrylamides, alkene-tethered 2-(2-i...

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Detalles Bibliográficos
Autores principales: Xu, Yankun, Xu, Weiwei, Chen, Xinyang, Luo, Xiai, Lu, Haiyan, Zhang, Minghao, Yang, Xiumei, Deng, Guobo, Liang, Yun, Yang, Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442712/
https://www.ncbi.nlm.nih.gov/pubmed/34659712
http://dx.doi.org/10.1039/d1sc03487a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442712/
https://www.ncbi.nlm.nih.gov/pubmed/34659712
http://dx.doi.org/10.1039/d1sc03487a

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