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Me(3)SiSiMe(2)(O(n)Bu): a disilane reagent for the synthesis of diverse silacycles via Brook- and retro-Brook-type rearrangement
Herein, a readily available disilane Me(3)SiSiMe(2)(O(n)Bu) has been developed for the synthesis of diverse silacycles via Brook- and retro-Brook-type rearrangement. This protocol enables the incorporation of a silylene into different starting materials, including acrylamides, alkene-tethered 2-(2-i...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8442712/ https://www.ncbi.nlm.nih.gov/pubmed/34659712 http://dx.doi.org/10.1039/d1sc03487a |