Reactivity of a Gold-Aluminyl Complex with Carbon Dioxide: A Nucleophilic Gold?

[Image: see text] A gold-aluminyl complex has been recently reported to feature an unconventional gold nucleophilic center, which was revealed through reactivity with carbon dioxide leading to the Au-CO(2) coordination mode. In this work, we computationally investigate the reaction mechanism, which...

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Detalles Bibliográficos
Autores principales: Sorbelli, Diego, Belpassi, Leonardo, Belanzoni, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8447181/
https://www.ncbi.nlm.nih.gov/pubmed/34472349
http://dx.doi.org/10.1021/jacs.1c06728