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Reactivity of a Gold-Aluminyl Complex with Carbon Dioxide: A Nucleophilic Gold?
[Image: see text] A gold-aluminyl complex has been recently reported to feature an unconventional gold nucleophilic center, which was revealed through reactivity with carbon dioxide leading to the Au-CO(2) coordination mode. In this work, we computationally investigate the reaction mechanism, which...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8447181/ https://www.ncbi.nlm.nih.gov/pubmed/34472349 http://dx.doi.org/10.1021/jacs.1c06728 |