Combining palladium and ammonium halide catalysts for Morita–Baylis–Hillman carbonates of methyl vinyl ketone: from 1,4-carbodipoles to ion pairs

Here we report that Morita–Baylis–Hillman carbonates from diverse aldehydes and methyl vinyl ketones can be directly utilised as palladium-trimethylenemethane 1,4-carbodipole-type precursors, and both reactivity and enantioselectivity are finely regulated by adding a chiral ammonium halide as the io...

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Detalles Bibliográficos
Autores principales: Yang, Yang, Zhu, Bo, Zhu, Lei, Jiang, Ying, Guo, Chun-Ling, Gu, Jing, Ouyang, Qin, Du, Wei, Chen, Ying-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8447884/
https://www.ncbi.nlm.nih.gov/pubmed/34667548
http://dx.doi.org/10.1039/d1sc03517g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8447884/
https://www.ncbi.nlm.nih.gov/pubmed/34667548
http://dx.doi.org/10.1039/d1sc03517g

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