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Early Oxidative Transformations During the Biosynthesis of Terrein and Related Natural Products
The mycotoxin terrein is derived from the C(10)‐precursor 6‐hydroxymellein (6‐HM) via an oxidative ring contraction. Although the corresponding biosynthetic gene cluster (BGC) has been identified, details of the enzymatic oxidative transformations are lacking. Combining heterologous expression and i...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453496/ https://www.ncbi.nlm.nih.gov/pubmed/34114710 http://dx.doi.org/10.1002/chem.202101447 |