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Reactivity of 5‐(Alkynyl)dibenzothiophenium Salts: Synthesis of Diynes, Vinyl Sulfones, and Phenanthrenes

The reactivity of 5‐(alkynyl)dibenzothiophenium salts 1 is explored in the presence of different nucleophiles, dienes, and under photochemical conditions. Reaction with lithium acetylides affords diynes in moderate yields; while depending on the substitution pattern, the reaction with sulfinates del...

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Detalles Bibliográficos
Autores principales: Kafuta, Kevin, Rugen, Christian J., Heilmann, Tobias, Liu, Tianshu, Golz, Christopher, Alcarazo, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453815/
https://www.ncbi.nlm.nih.gov/pubmed/34588919
http://dx.doi.org/10.1002/ejoc.202100323