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E(4) Transfer (E=P, As) to Ni Complexes

The use of [Cp′′(2)Zr(η(1:1)‐E(4))] (E=P (1 a), As (1 b), Cp′′=1,3‐di‐tert‐butyl‐cyclopentadienyl) as phosphorus or arsenic source, respectively, gives access to novel stable polypnictogen transition metal complexes at ambient temperatures. The reaction of 1 a/1 b with [Cp(R)NiBr](2) (Cp(R)=Cp(Bn) (...

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Detalles Bibliográficos
Autores principales: Heinl, Veronika, Schmidt, Monika, Eckhardt, Maria, Eberl, Miriam, Seitz, Andreas E., Balázs, Gábor, Seidl, Michael, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453863/
https://www.ncbi.nlm.nih.gov/pubmed/33971062
http://dx.doi.org/10.1002/chem.202101119