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The Stronger the Better: Donor Substituents Push Catalytic Activity of Molecular Chromium Olefin Polymerization Catalysts

The donor strength of bifunctional pyridine‐cyclopentadienyl ligands was altered systematically by the introduction of donating groups in the para‐position of the pyridine. In the resulting chromium complexes an almost linear correlation between donor strength and the nitrogen‐chromium distance as w...

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Detalles Bibliográficos
Autores principales: Hansen, Helge‐Boj, Wadepohl, Hubert, Enders, Markus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453878/
https://www.ncbi.nlm.nih.gov/pubmed/34018643
http://dx.doi.org/10.1002/chem.202101586