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Radicals and Anions of Siloles and Germoles

The synthesis of persistent sila‐ and germacyclopentadienyl (silolyl‐ and germolyl‐) radicals by careful stoichiometric reduction of the corresponding halides with potassium is reported. The radicals were characterized by EPR spectroscopy and trapping reactions. The reduction of tris(trimethylsilyl)...

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Detalles Bibliográficos
Autores principales: Reinhold, Crispin R. W., Schmidtmann, Marc, Tumanskii, Boris, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8453960/
https://www.ncbi.nlm.nih.gov/pubmed/33978965
http://dx.doi.org/10.1002/chem.202101415