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Photoinduced Low-Spin → High-Spin Mechanism of an Octahedral Fe(II) Complex Revealed by Synergistic Spin-Vibronic Dynamics
[Image: see text] The Fe(II) low-spin (LS; (1)A(1g), t(2g)(6)e(g)(0)) → high-spin (HS; (5)T(2g), t(2g)(4)e(g)(2)) light-induced excited spin state trapping (LIESST) mechanism solely involving metal-centered states is revealed by synergistic spin-vibronic dynamics simulations. For the octahedral [Fe(...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456406/ https://www.ncbi.nlm.nih.gov/pubmed/34498843 http://dx.doi.org/10.1021/acs.inorgchem.1c01838 |