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Nickel‐Catalyzed Thiolation of Aryl Nitriles

A nickel‐catalyzed thiolation of aryl nitriles has been developed to access functionalized aryl thioethers. The ligand dcype (1,2‐bis(dicyclohexylphosphino)ethane) as well as the base KO(t)Bu (potassium tert‐butoxide) are essential to achieve this transformation. This scalable and practical process...

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Detalles Bibliográficos
Autores principales: Delcaillau, Tristan, Morandi, Bill
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456793/
https://www.ncbi.nlm.nih.gov/pubmed/34114686
http://dx.doi.org/10.1002/chem.202101273