Beyond Takai's Olefination Reagent: Persistent Dehalogenation Emerges in a Chromium(III)‐μ(3)‐Methylidyne Complex

Reaction of CHI(3) with six equivalents of CrCl(2) in THF at low temperatures affords [Cr(3)Cl(3)(μ(2)‐Cl)(3)(μ(3)‐CH)(thf)(6)] as the first isolable high‐yield Cr(III) μ(3)‐methylidyne complex. Substitution of the terminal chlorido ligands via salt metathesis with alkali‐metal cyclopentadienides ge...

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Detalles Bibliográficos
Autores principales: Trzmiel, Simon, Langmann, Jan, Werner, Daniel, Maichle‐Mössmer, Cäcilia, Scherer, Wolfgang, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456800/
https://www.ncbi.nlm.nih.gov/pubmed/34213805
http://dx.doi.org/10.1002/anie.202106608

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456800/
https://www.ncbi.nlm.nih.gov/pubmed/34213805
http://dx.doi.org/10.1002/anie.202106608

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