The Hydrates of TEMPO: Water Vibrations Reveal Radical Microsolvation

An organic radical monohydrate complex is detected in vacuum isolation at low temperature by FTIR supersonic jet spectroscopy for the first time. It is shown to exhibit a rich conformational and vibrational coupling dynamics, which can be drastically reduced by appropriate isotope substitution. Its...

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Detalles Bibliográficos
Autores principales: Brás, Elisa M., Fischer, Taija L., Suhm, Martin A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456822/
https://www.ncbi.nlm.nih.gov/pubmed/34165885
http://dx.doi.org/10.1002/anie.202104496