A Chemiluminescent Tetraaryl Diborane(4) Tetraanion

Two subvalent, redox‐active diborane(4) anions, [3](4−) and [3](2−), carrying exceptionally high negative charge densities are reported: Reduction of 9‐methoxy‐9‐borafluorene with Li granules without stirring leads to the crystallization of the B(sp(3))−B(sp(2)) diborane(5) anion salt Li[5]. [5](−)...

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Detalles Bibliográficos
Autores principales: Budy, Hendrik, Kaese, Thomas, Bolte, Michael, Lerner, Hans‐Wolfram, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456833/
https://www.ncbi.nlm.nih.gov/pubmed/34161639
http://dx.doi.org/10.1002/anie.202106980

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456833/
https://www.ncbi.nlm.nih.gov/pubmed/34161639
http://dx.doi.org/10.1002/anie.202106980

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