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Photo Click Reaction of Acylsilanes with Indoles

Light‐mediated coupling of acylsilanes with indoles is reported. This photo click reaction occurs under mild conditions (415 nm) mostly in quantitative yield and provides stable silylated N,O‐acetals via light mediated siloxycarbene generation with subsequent indole‐N‐H insertion. We show that this...

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Detalles Bibliográficos
Autores principales: Stuckhardt, Constantin, Wissing, Maren, Studer, Armido
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456837/
https://www.ncbi.nlm.nih.gov/pubmed/34129264
http://dx.doi.org/10.1002/anie.202101689