Chemoselective γ‐Oxidation of β,γ‐Unsaturated Amides with TEMPO

A chemoselective and robust protocol for the γ‐oxidation of β,γ‐unsaturated amides is reported. In this method, electrophilic amide activation, in a rare application to unsaturated amides, enables a regioselective reaction with TEMPO resulting in the title products. Radical cyclisation reactions and...

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Detalles Bibliográficos
Autores principales: Heindl, Sebastian, Riomet, Margaux, Matyasovsky, Ján, Lemmerer, Miran, Malzer, Nicolas, Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456850/
https://www.ncbi.nlm.nih.gov/pubmed/34146371
http://dx.doi.org/10.1002/anie.202104023

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456850/
https://www.ncbi.nlm.nih.gov/pubmed/34146371
http://dx.doi.org/10.1002/anie.202104023

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