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A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds

Herein, we report the preparation of silver(I) pentafluorooxosulfate from commercially available AgF and OSF(4). The compound is surprisingly stable in a MeCN solution. Apart from that, AgOSF(5) has been stabilised by the addition of 2,2′‐bipyridine ligands. Starting from solutions of the unstabilis...

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Detalles Bibliográficos
Autores principales: Haupt, Axel, Duvinage, Daniel, Lork, Enno, Ponomarenko, Maksym, Röschenthaler, Gerd‐Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456853/
https://www.ncbi.nlm.nih.gov/pubmed/34165887
http://dx.doi.org/10.1002/anie.202107587