A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds

Herein, we report the preparation of silver(I) pentafluorooxosulfate from commercially available AgF and OSF(4). The compound is surprisingly stable in a MeCN solution. Apart from that, AgOSF(5) has been stabilised by the addition of 2,2′‐bipyridine ligands. Starting from solutions of the unstabilis...

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Autores principales: Haupt, Axel, Duvinage, Daniel, Lork, Enno, Ponomarenko, Maksym, Röschenthaler, Gerd‐Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456853/
https://www.ncbi.nlm.nih.gov/pubmed/34165887
http://dx.doi.org/10.1002/anie.202107587
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author Haupt, Axel
Duvinage, Daniel
Lork, Enno
Ponomarenko, Maksym
Röschenthaler, Gerd‐Volker
author_facet Haupt, Axel
Duvinage, Daniel
Lork, Enno
Ponomarenko, Maksym
Röschenthaler, Gerd‐Volker
author_sort Haupt, Axel
collection PubMed
description Herein, we report the preparation of silver(I) pentafluorooxosulfate from commercially available AgF and OSF(4). The compound is surprisingly stable in a MeCN solution. Apart from that, AgOSF(5) has been stabilised by the addition of 2,2′‐bipyridine ligands. Starting from solutions of the unstabilised silver(I) salt, OSF(5) complexes with Ni(II), Cu(I), and Cu(II)‐centres have been obtained. In addition, AgOSF(5) has proven to be generally capable of mediating the transfer of OSF(5) groups to aryne moieties, thus furnishing a new and safe method for the preparation of OSF(5)‐substituted arenes. X‐ray crystal structure analysis of selected transition‐metal OSF(5) compounds have revealed distorted octahedral [OSF(5)](−) anions which are extensively stabilised by hydrogen bonding.
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spelling pubmed-84568532021-09-27 A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds Haupt, Axel Duvinage, Daniel Lork, Enno Ponomarenko, Maksym Röschenthaler, Gerd‐Volker Angew Chem Int Ed Engl Communications Herein, we report the preparation of silver(I) pentafluorooxosulfate from commercially available AgF and OSF(4). The compound is surprisingly stable in a MeCN solution. Apart from that, AgOSF(5) has been stabilised by the addition of 2,2′‐bipyridine ligands. Starting from solutions of the unstabilised silver(I) salt, OSF(5) complexes with Ni(II), Cu(I), and Cu(II)‐centres have been obtained. In addition, AgOSF(5) has proven to be generally capable of mediating the transfer of OSF(5) groups to aryne moieties, thus furnishing a new and safe method for the preparation of OSF(5)‐substituted arenes. X‐ray crystal structure analysis of selected transition‐metal OSF(5) compounds have revealed distorted octahedral [OSF(5)](−) anions which are extensively stabilised by hydrogen bonding. John Wiley and Sons Inc. 2021-07-09 2021-08-09 /pmc/articles/PMC8456853/ /pubmed/34165887 http://dx.doi.org/10.1002/anie.202107587 Text en © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Haupt, Axel
Duvinage, Daniel
Lork, Enno
Ponomarenko, Maksym
Röschenthaler, Gerd‐Volker
A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
title A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
title_full A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
title_fullStr A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
title_full_unstemmed A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
title_short A Versatile Silver(I) Pentafluorooxosulfate Reagent for the Synthesis of OSF(5) Compounds
title_sort versatile silver(i) pentafluorooxosulfate reagent for the synthesis of osf(5) compounds
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456853/
https://www.ncbi.nlm.nih.gov/pubmed/34165887
http://dx.doi.org/10.1002/anie.202107587
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