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Simple Accurate Verification of Enthalpy‐Entropy Compensation and Isoequilibrium Relationship

In many experimental investigations of thermodynamic equilibrium or kinetic properties of series of similar reactions it is found that the enthalpies and entropies derived from Van ′t Hoff or Arrhenius plots exhibit a strong linear correlation. The origin of this Enthalpy‐Entropy compensation, which...

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Detalles Bibliográficos
Autores principales: Griessen, Ronald, Dam, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456872/
https://www.ncbi.nlm.nih.gov/pubmed/34213060
http://dx.doi.org/10.1002/cphc.202100431