Highly Enantioselective Iridium(I)‐Catalyzed Hydrocarbonation of Alkenes: A Versatile Approach to Heterocyclic Systems Bearing Quaternary Stereocenters

We report a versatile, highly enantioselective intramolecular hydrocarbonation reaction that provides a direct access to heteropolycyclic systems bearing chiral quaternary carbon stereocenters. The method, which relies on an iridium(I)/bisphosphine chiral catalyst, is particularly efficient for the...

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Detalles Bibliográficos
Autores principales: Arribas, Andrés, Calvelo, Martín, Fernández, David F., Rodrigues, Catarina A. B., Mascareñas, José L., López, Fernando
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456945/
https://www.ncbi.nlm.nih.gov/pubmed/34137152
http://dx.doi.org/10.1002/anie.202105776

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456945/
https://www.ncbi.nlm.nih.gov/pubmed/34137152
http://dx.doi.org/10.1002/anie.202105776

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