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Highly Enantioselective Iridium(I)‐Catalyzed Hydrocarbonation of Alkenes: A Versatile Approach to Heterocyclic Systems Bearing Quaternary Stereocenters
We report a versatile, highly enantioselective intramolecular hydrocarbonation reaction that provides a direct access to heteropolycyclic systems bearing chiral quaternary carbon stereocenters. The method, which relies on an iridium(I)/bisphosphine chiral catalyst, is particularly efficient for the...
Autores principales: | Arribas, Andrés, Calvelo, Martín, Fernández, David F., Rodrigues, Catarina A. B., Mascareñas, José L., López, Fernando |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456945/ https://www.ncbi.nlm.nih.gov/pubmed/34137152 http://dx.doi.org/10.1002/anie.202105776 |
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