Identification of M‐NH(2)‐NH(2) Intermediate and Rate Determining Step for Nitrogen Reduction with Bioinspired Sulfur‐Bonded FeW Catalyst

The multimetallic sulfur‐framework catalytic site of biological nitrogenases allows the efficient conversion of dinitrogen (N(2)) to ammonia (NH(3)) under ambient conditions. Inspired by biological nitrogenases, a bimetallic sulfide material (FeWS(x)@FeWO(4)) was synthesized as a highly efficient N(...

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Detalles Bibliográficos
Autores principales: Zhao, Yilong, Li, Fusheng, Li, Wenlong, Li, Yingzheng, Liu, Chang, Zhao, Ziqi, Shan, Yu, Ji, Yongfei, Sun, Licheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456964/
https://www.ncbi.nlm.nih.gov/pubmed/34245082
http://dx.doi.org/10.1002/anie.202104918

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456964/
https://www.ncbi.nlm.nih.gov/pubmed/34245082
http://dx.doi.org/10.1002/anie.202104918

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