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Alkene Isomerization Revitalizes the Coates–Claisen Rearrangement

The [3,3]‐sigmatropic rearrangement of allylic vinyl acetals, first investigated by Coates nearly four decades ago, is set apart from other variants of the Claisen rearrangement owing to the versatile monoprotected 1,5‐dicarbonyl motif featured in the products. Unfortunately, the synthetically elusi...

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Detalles Bibliográficos
Autores principales: Massad, Itai, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456971/
https://www.ncbi.nlm.nih.gov/pubmed/34133046
http://dx.doi.org/10.1002/anie.202105834