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Pathways of the Extremely Reactive Iron(IV)‐oxido complexes with Tetradentate Bispidine Ligands

The nonheme iron(IV)‐oxido complex trans‐N3‐[(L(1))Fe(IV)=O(Cl)](+), where L(1) is a derivative of the tetradentate bispidine 2,4‐di(pyridine‐2‐yl)‐3,7‐diazabicyclo[3.3.1]nonane‐1‐one, is known to have an S=1 electronic ground state and to be an extremely reactive oxidant for oxygen atom transfer (O...

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Detalles Bibliográficos
Autores principales: Abu‐Odeh, Mahmud, Bleher, Katharina, Johnee Britto, Neethinathan, Comba, Peter, Gast, Michael, Jaccob, Madhavan, Kerscher, Marion, Krieg, Saskia, Kurth, Marius
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8456976/
https://www.ncbi.nlm.nih.gov/pubmed/34121233
http://dx.doi.org/10.1002/chem.202101045