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Cooperative Effects in Switchable Catalysis: Enhancing Double‐Click Reaction Yield of Symmetrical Rotaxanes

Reversible switching between the closed cyclic dimeric assembly [Cu(2)(1)(2)](2+) (OFF state) and the extended dimeric homoleptic complex [FeCu(2)(1)(2)](4+) (ON State) by addition/removal of Fe(2+) triggered catalysis of a double‐click reaction and high yield preparation of [2]rotaxanes. Mechanisti...

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Detalles Bibliográficos
Autores principales: Ghosh, Amit, Paul, Indrajit, Schmittel, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457069/
https://www.ncbi.nlm.nih.gov/pubmed/34289211
http://dx.doi.org/10.1002/anie.202108269