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Cooperative Effects in Switchable Catalysis: Enhancing Double‐Click Reaction Yield of Symmetrical Rotaxanes
Reversible switching between the closed cyclic dimeric assembly [Cu(2)(1)(2)](2+) (OFF state) and the extended dimeric homoleptic complex [FeCu(2)(1)(2)](4+) (ON State) by addition/removal of Fe(2+) triggered catalysis of a double‐click reaction and high yield preparation of [2]rotaxanes. Mechanisti...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457069/ https://www.ncbi.nlm.nih.gov/pubmed/34289211 http://dx.doi.org/10.1002/anie.202108269 |