Cargando…
High‐Spin Iron(VI), Low‐Spin Ruthenium(VI), and Magnetically Bistable Osmium(VI) in Molecular Group 8 Nitrido Trifluorides NMF(3)
Pseudo‐tetrahedral nitrido trifluorides N≡MF(3) (M=Fe, Ru, Os) and square pyramidal nitrido tetrafluorides N≡MF(4) (M=Ru, Os) were formed by free‐metal‐atom reactions with NF(3) and subsequently isolated in solid neon at 5 K. Their IR spectra were recorded and analyzed aided by quantum‐chemical calc...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457171/ https://www.ncbi.nlm.nih.gov/pubmed/34043842 http://dx.doi.org/10.1002/chem.202101404 |