Polymerization of Allenes by Using an Iron(II) β‐Diketiminate Pre‐Catalyst to Generate High M (n) Polymers

Herein, we report an iron(II)‐catalyzed polymerization of arylallenes. This reaction proceeds rapidly at room temperature in the presence of a hydride co‐catalyst to generate polymers of weight up to M (n)=189 000 Da. We have determined the polymer structure and chain length for a range of monomers...

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Detalles Bibliográficos
Autores principales: Woof, Callum R., Durand, Derek J., Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457186/
https://www.ncbi.nlm.nih.gov/pubmed/34143554
http://dx.doi.org/10.1002/chem.202101078

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457186/
https://www.ncbi.nlm.nih.gov/pubmed/34143554
http://dx.doi.org/10.1002/chem.202101078

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