New‐Generation Ligand Design for the Gold‐Catalyzed Asymmetric Activation of Alkynes

Gold(I) catalysts are ideal for the activation of alkynes under very mild conditions. However, unlike allenes or alkenes, the triple bond of alkynes cannot be prochiral. In addition, the linear coordination displayed by gold(I) complexes places the chiral ligand far away from the substrate resulting...

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Detalles Bibliográficos
Autores principales: Zuccarello, Giuseppe, Escofet, Imma, Caniparoli, Ulysse, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Minireviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457203/
https://www.ncbi.nlm.nih.gov/pubmed/34472729
http://dx.doi.org/10.1002/cplu.202100232

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457203/
https://www.ncbi.nlm.nih.gov/pubmed/34472729
http://dx.doi.org/10.1002/cplu.202100232

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