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New‐Generation Ligand Design for the Gold‐Catalyzed Asymmetric Activation of Alkynes
Gold(I) catalysts are ideal for the activation of alkynes under very mild conditions. However, unlike allenes or alkenes, the triple bond of alkynes cannot be prochiral. In addition, the linear coordination displayed by gold(I) complexes places the chiral ligand far away from the substrate resulting...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457203/ https://www.ncbi.nlm.nih.gov/pubmed/34472729 http://dx.doi.org/10.1002/cplu.202100232 |