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Evolution of a Strategy for the Total Synthesis of (+)‐Cornexistin

Herein is given a full account of the evolution of the first total synthesis of (+)‐cornexistin. Initial efforts were based on masking the reactive maleic anhydride moiety as a 3,4‐substituted furan and on forming the nine‐membered carbocycle in an intramolecular Conia‐ene or Nozaki–Hiyama–Kishi (NH...

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Detalles Bibliográficos
Autores principales: Wildermuth, Raphael E., Steinborn, Christian, Barber, David M., Mühlfenzl, Kim S., Kendlbacher, Mario, Mayer, Peter, Wurst, Klaus, Magauer, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457225/
https://www.ncbi.nlm.nih.gov/pubmed/34105834
http://dx.doi.org/10.1002/chem.202101849