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Biomimetic Total Synthesis of Enterocin

The first chemical total synthesis of the highly oxygenated polyketide enterocin has been accomplished. The key step of the synthesis was a late‐stage biomimetic reaction cascade involving two intramolecular aldol reactions in which each step proceeded in 52 % yield (averaged) and which established...

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Detalles Bibliográficos
Autores principales: Koser, Lilla, Lechner, Vivian Miles, Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457242/
https://www.ncbi.nlm.nih.gov/pubmed/34278701
http://dx.doi.org/10.1002/anie.202108157