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Silver‐Free Au(I) Catalysis Enabled by Bifunctional Urea‐ and Squaramide‐Phosphine Ligands via H‐Bonding

A library of gold(I) chloride complexes with phosphine ligands incorporating pendant (thio)urea and squaramide H‐bond donors was prepared with the aim of promoting chloride abstraction from Au(I) via H‐bonding. In the absence of silver additives, complexes bearing squaramides and trifluoromethylated...

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Detalles Bibliográficos
Autores principales: Franchino, Allegra, Martí, Àlex, Nejrotti, Stefano, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457243/
https://www.ncbi.nlm.nih.gov/pubmed/34018646
http://dx.doi.org/10.1002/chem.202101751