Copper‐Catalyzed Dehydrogenative Amidation of Light Alkanes

The functionalization of C−H bonds in light alkanes, particularly to form C−N bonds, remains a challenge. We report the dehydrogenative coupling of amides with C1–C4 hydrocarbons to form N‐alkyl amide products with tBuOOtBu as oxidant, and a copper complex of a phenanthroline‐type ligand as catalyst...

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Detalles Bibliográficos
Autores principales: Fuentes, M. Ángeles, Gava, Riccardo, Saper, Noam I., Romero, Erik A., Caballero, Ana, Hartwig, John F., Pérez, Pedro J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457245/
https://www.ncbi.nlm.nih.gov/pubmed/33979475
http://dx.doi.org/10.1002/anie.202104737

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457245/
https://www.ncbi.nlm.nih.gov/pubmed/33979475
http://dx.doi.org/10.1002/anie.202104737

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