Origin of asynchronicity in Diels–Alder reactions

Asynchronicity in Diels–Alder reactions plays a crucial role in determining the height of the reaction barrier. Currently, the origin of asynchronicity is ascribed to the stronger orbital interaction between the diene and the terminal carbon of an asymmetric dienophile, which shortens the correspond...

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Detalles Bibliográficos
Autores principales: Vermeeren, Pascal, Hamlin, Trevor A., Bickelhaupt, F. Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457343/
https://www.ncbi.nlm.nih.gov/pubmed/34499069
http://dx.doi.org/10.1039/d1cp02456f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457343/
https://www.ncbi.nlm.nih.gov/pubmed/34499069
http://dx.doi.org/10.1039/d1cp02456f

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