Hydrofluoromethylation of alkenes with fluoroiodomethane and beyond

A process for the direct hydrofluoromethylation of alkenes is reported for the first time. This straighforward silyl radical-mediated reaction utilises CH(2)FI as a non-ozone depleting reagent, traditionally used in electrophilic, nucleophilic and carbene-type chemistry, but not as a CH(2)F radical...

Descripción completa

Detalles Bibliográficos
Autores principales: Hell, Sandrine M., Meyer, Claudio F., Ortalli, Sebastiano, Sap, Jeroen B. I., Chen, Xuanxiao, Gouverneur, Véronique
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457377/
https://www.ncbi.nlm.nih.gov/pubmed/34667580
http://dx.doi.org/10.1039/d1sc03421a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8457377/
https://www.ncbi.nlm.nih.gov/pubmed/34667580
http://dx.doi.org/10.1039/d1sc03421a

Ejemplares similares