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Isomers of the Allyl Carbocation C(3)H(5)(+) in Solid Salts: Infrared Spectra and Structures

[Image: see text] Three isomers of the allyl cation C(3)H(5)(+) were obtained in salts with the carborane anion CHB(11)Cl(11)(–). Two of them, angular CH(3)–CH=CH(+) (I) and linear CH(3)–C(+)=CH(2) (II), were characterized by X-ray crystallography, and the third one, (CH(2)CHCH(2))(+) (III), is form...

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Detalles Bibliográficos
Autores principales: Stoyanov, Evgenii S., Bagryanskaya, Irina Yu., Stoyanova, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8459358/
https://www.ncbi.nlm.nih.gov/pubmed/34568649
http://dx.doi.org/10.1021/acsomega.1c01316