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Palladium-catalyzed regio- and enantioselective migratory allylic C(sp(3))-H functionalization

Transition metal-catalyzed asymmetric allylic substitution with a suitably pre-stored leaving group in the substrate is widely used in organic synthesis. In contrast, the enantioselective allylic C(sp(3))-H functionalization is more straightforward but far less explored. Here we report a catalytic p...

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Detalles Bibliográficos
Autores principales: Chen, Ye-Wei, Liu, Yang, Lu, Han-Yu, Lin, Guo-Qiang, He, Zhi-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8463607/
https://www.ncbi.nlm.nih.gov/pubmed/34561444
http://dx.doi.org/10.1038/s41467-021-25978-6