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Exceptional uranium(VI)-nitride triple bond covalency from (15)N nuclear magnetic resonance spectroscopy and quantum chemical analysis
Determining the nature and extent of covalency of early actinide chemical bonding is a fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and nuclear magnetic resonance spectroscopic studies have probed actinide-ligand covalency, largely confirming the paradigm of...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8463702/ https://www.ncbi.nlm.nih.gov/pubmed/34561448 http://dx.doi.org/10.1038/s41467-021-25863-2 |