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γ-Selective C(sp(3))–H amination via controlled migratory hydroamination
Remote functionalization of alkenes via chain walking has generally been limited to C(sp(3))–H bonds α and β to polar-functional units, while γ-C(sp(3))–H functionalization through controlled alkene transposition is a longstanding challenge. Herein, we describe NiH-catalyzed migratory formal hydroam...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8476554/ https://www.ncbi.nlm.nih.gov/pubmed/34580295 http://dx.doi.org/10.1038/s41467-021-25696-z |