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γ-Selective C(sp(3))–H amination via controlled migratory hydroamination

Remote functionalization of alkenes via chain walking has generally been limited to C(sp(3))–H bonds α and β to polar-functional units, while γ-C(sp(3))–H functionalization through controlled alkene transposition is a longstanding challenge. Herein, we describe NiH-catalyzed migratory formal hydroam...

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Detalles Bibliográficos
Autores principales: Lee, Changseok, Seo, Huiyeong, Jeon, Jinwon, Hong, Sungwoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8476554/
https://www.ncbi.nlm.nih.gov/pubmed/34580295
http://dx.doi.org/10.1038/s41467-021-25696-z