Structural and Spectroscopic Evidence for a Side-on Fe(III)–Superoxo Complex Featuring Discrete O–O Bond Distances

[Image: see text] The O–O bond length is often used as a structural indicator to determine the valence states of bound O(2) ligands in biological metal–dioxygen intermediates and related biomimetic complexes. Here, we report very distinct O–O bond lengths found for three crystallographic forms (1.22...

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Detalles Bibliográficos
Autores principales: Pan, Hung-Ruei, Chen, Hsin-Jou, Wu, Zong-Han, Ge, Pu, Ye, Shengfa, Lee, Gene-Hsiang, Hsu, Hua-Fen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479760/
https://www.ncbi.nlm.nih.gov/pubmed/34604849
http://dx.doi.org/10.1021/jacsau.1c00184

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8479760/
https://www.ncbi.nlm.nih.gov/pubmed/34604849
http://dx.doi.org/10.1021/jacsau.1c00184

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