β-Trioxopyrrocorphins: pyrrocorphins of graded aromaticity

Octaethyltrioxopyrrocorphins unexpectedly show macrocycle-aromatic properties, even though they contain the macrocyclic π-system of the non-aromatic pyrrocorphins (hexahydroporphyrins). Two of the four possible triketone regioisomers were first reported in 1969 by one-pot oxidation of octaethylporph...

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Detalles Bibliográficos
Autores principales: Chaudhri, Nivedita, Guberman-Pfeffer, Matthew J., Li, Ruoshi, Zeller, Matthias, Brückner, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8480330/
https://www.ncbi.nlm.nih.gov/pubmed/34603659
http://dx.doi.org/10.1039/d1sc03403k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8480330/
https://www.ncbi.nlm.nih.gov/pubmed/34603659
http://dx.doi.org/10.1039/d1sc03403k

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