Insights into the Observed trans-Bond Length Variations upon NO Binding to Ferric and Ferrous Porphyrins with Neutral Axial Ligands

[Image: see text] NO is well-known for its trans effect. NO binding to ferrous hemes of the form (por)Fe(L) (L = neutral N-based ligand) to give the {FeNO}(7) (por)Fe(NO)(L) product results in a lengthening of the axial trans Fe–L bond. In contrast, NO binding to the ferric center in [(por)Fe(L)](+)...

Descripción completa

Detalles Bibliográficos
Autores principales: Khade, Rahul L., Abucayon, Erwin G., Powell, Douglas R., Richter-Addo, George B., Zhang, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8482462/
https://www.ncbi.nlm.nih.gov/pubmed/34604659
http://dx.doi.org/10.1021/acsomega.1c03610

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8482462/
https://www.ncbi.nlm.nih.gov/pubmed/34604659
http://dx.doi.org/10.1021/acsomega.1c03610

Ejemplares similares