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Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus

The synthesis of phosphines is based on white phosphorus, which is usually converted to PCl(3), to be afterwards substituted step by step in a non-atomic efficient manner. Herein, we describe an alternative efficient transition metal-mediated process to form asymmetrically substituted phosphines dir...

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Detalles Bibliográficos
Autores principales: Reichl, Stephan, Mädl, Eric, Riedlberger, Felix, Piesch, Martin, Balázs, Gábor, Seidl, Michael, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8486752/
https://www.ncbi.nlm.nih.gov/pubmed/34599185
http://dx.doi.org/10.1038/s41467-021-26002-7